@stephen-w-towle - good question. I generally prime small stuff in black and then do a Zenithal highlight in white from the top to establish basic highlight and shadow. These are large enough that that doesn't work as well. The trooper is currently primed Grey but the plan is to spray him with a White rattlecan. I'll then hand paint the details. like the black of the undersuit and the leather pouches. This trooper will also have a Grey pauldron. After everything is base coated I'll hit him with gloss to make his armor look new (brush paint a flat over the non armor parts). Then follow that with a ton of weathering. I usually use Citadel shades like Agrax Earthshade and old conte crayons from when I was in college. They make great weathering powders.
The dewback will like be a very different process. I've already given him a base coat of Citadel, Steel Legion Drab. I'm planning on going over it with thinned down colors like Citadel's Deathguard Green And Deathworld Forest. Maybe some Vallejo Camouflage Green... I want to go a bit light on this stage so when I go back in with the shades to enhance the gaps between scales it doesn't darken him too much. Then there will likely be some dry brushing with some tans and pale greens. After all of that it's painting the leathers. It's always fun to add the little cracks and details in leather.
The scale really matters though. On 35mm minis you have to emphasize the volumes so the viewer can actually see stuff. Something this big, the room lights actually make the shadows for you so they only get minimally enhanced.
2 attached images. Click to enlarge.